CHEM 235 - EXP.2 - EXTRACTION

Liquid-liquid extractio

6 cards   |   Total Attempts: 190
  

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BASED ON WHAT PROPERTIES DOES LIQUID-LIQUID EXTRACTION USE TO SEPERATE MIXTURES?
Seperates the two immiscible solvents based on solubility differences.
WHAT ARE THE CHARACTERISITICS TWO SOLVENTS MUST HAVE IN ORDER TO SEPERATE VIA LIQUID-LIQUID EXTRACTION?
I) They cannot be miscible with each other.
ii) First solvent should completely dissolve both compounds (can work with one compound suspended).
iii) The second solvent should dissolve only one component.
WHAT IS THE PARTITION COEFFICIENT?
- In an equilibrium state of the solute between the two solvents, the ratio of concentration between the two solvents are constant.
- This occurs after mixing the solute in the immiscible solvent.
- The solute is still dissolve-able in both layers even though one is preferred.
WHAT ARE SOME METHODS FOR REMOVAL OF AN ORGANIC SOLVENT FROM THE DESIRED COMPOUND?
1) Evaporation on steam bath or hot water bath.
2) Evaporation at reduced pressure.
3) Distillation
4) Evaporation by means of rotary evaporator.
WHAT IS THE CORRECT METHOD OF USING LITMUS PAPER TO TEST FOR ACIDITY OR BASICITY?
Stir the solution with a glass rod and pull it up from the center of the solution and touch the litmus paper with the tip.
Never stick the litmus paper into the solution!
WHAT IS THE PARTITION COEFFICIENT?
K = C2/C1
C1 is equilibrium concentration of solute A in solvent 1
C2 is equilibrium concentration of solute A in solvent 2