Functional Group Chemistry

56 cards | Total Attempts: 182 | Created by amyra101 | Last updated: Feb 14, 2019 | Total Attempts: 182

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Functional Group Chemistry - Flashcards

Hydrocarbon Compounds

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Cards In This Set

Front	Back
hydrocarbon compounds	compounds that contain only Carbon and hydrogen atoms
alkane	branched, straight chain or cyclic saturated- only single bonds formula-CnH2n+2 Pka- >50 react poorly with ionic or polar solvents substances (chemically inactive) virtually insoluble in water Pka >50 physical properties M.P/B.P increases with increasing carbon chain due to (weak London dispersion intermolecular forces between substances where there is no permanent dipole) Reactivity Generally unreactive combustion (burn in a flame) Halogenation (Cl2/Br2) at high temps or high energy light involving radicals proceeding through radical mechanism mechanism initiation-formation of radical propagation-radical used to make another termination-combo of two radical produce a neutral species radical stability the more CH3 groups that can participate in hyperconjugation the more stable the intermediate radical is distribution patterns of product determined by the stability of the intermediate radical number of carbon atoms bonded to the carbon with the lone electron determines what kind of radical it will be ie 3= tertiary 2=secondary 1=primary 0=methyl
Alkene	Eafe
Alkyne	Efe
Halide	Efe
Ether	Efef
Thioether	Efe
Disulfide	Efe
Sulfonium salt	Efef
Primary alcohol	Efeqf
Secondary alcohol	Efe
Tertiary alcohol	Ef
Phenol	Efe
Phenolate	Efef
Thiol	Efe