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Cards In This Set
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MCPBA
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Attacks double bonds, form epoxides
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Osmium Tetroxide + H2O2
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Yields syn addition of 2 alcohol groups
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Hg(OAc)2 + NaBH4 + -HO
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Yields an Markovian, anti addition of OH and H
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BH3:THF
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Yields an anti-markovian, syn addition of OH & H
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Hydride Shifts
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Move to create MORE STABLE carbocations (substituted) and double bonds
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H+ ions (from strong acids)
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Attack epoxides to form OH groups
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H2O
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O will attack + charges and lose an H to form an alcohol
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R2
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Yields anti addition to a double bond
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OH + Halohydrin
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Attacks alcohol group, halogen leaves; forms epoxide group
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H2CN2
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Forms carbene group; attacks double bond to form 3 member ring
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Anions
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Take H+ to form double bonds
take R groups to form double bonds normally attached to Na+ or K+, etc. |
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R2 + OH
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Form halohydrins
OH can be derived from H2O |
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Bulky bases
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Attache to least substituted carbon -- size of the base & interference of orbitals prevents bonding
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H2SO4
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Remove alcohol groups
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H2 + lindler's Catalyst
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Syn addition of 1 pair of Hydrogens to an alkyne to from an alkene
DOES NOT FORM AN ALKANE |
