Organic Chemistry Reactions

Organic chemistry Exam 2...

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Cards In This Set

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Radical reaction
alkanes: R-R
reagent
Cl2, Br2 and uv light
Radical reaction
ALKENES : R2C=CR2

Product
Chloro/bromoalkanes
Electrophilic addition
ALKENES : R2C=CR2

reagent
HX Br2, Cl2 in CCl4 H2O/H+
Electrophilic addition
ALKENES : R2C=CR2

Product
alkyl halide dihaloalkane alcohol
Oxymercuration/demerc.

ALKENES : R2C=CR2
reagent
1. Hg(OAc)2/THF/H2O 2. NaBH4, OH-
Oxymercuration/demerc.

ALKENES : R2C=CR2
product
alcohol (Markov.)
Hydroboration/oxidation

ALKENES : R2C=CR2
reagent
1. BH3/THF 2. H2O2 / OH –
Hydroboration/oxidation
ALKENES : R2C=CR2

product
alcohol (anti-Markov.)
Hydroxylation

ALKENES : R2C=CR2
reagent
OsO4 / NaHSO3
Hydroxylation

ALKENES : R2C=CR2
product
1,2-diol
Hydroxylation

ALKENES : R2C=CR2
reagent
KMnO4 / OH- / COLD
Hydroxylation

ALKENES : R2C=CR2
product
1,2-diol
HydrogenationALKENES : R2C=CR2Reagent
H2/Pt (or Pd)
Oxidative cleavageALKENES : R2C=CR2reagent
KMnO4 / OH- / HEAT
Oxidative cleavageALKENES : R2C=CR2 product
carboxylic acids, ketones, CO2